Chemical Reactions and Energy
Chemical reactions are processes that involve the rearrangement of atoms and molecules. They can be classified as either exothermic or endothermic, depending on whether they release or absorb energy.
Exothermic reactions release energy to the surroundings, often in the form of heat, light, or sound. The products have lower energy than the reactants. Examples of exothermic reactions include combustion (e.g., burning wood, propane gas), the neutralization of an acid and a base, and many oxidation reactions (e.g., rusting).
Endothermic reactions absorb energy from their surroundings. The products have higher energy than the reactants. The energy is often supplied as heat, but it could also be supplied as light or electricity. Examples of endothermic reactions include photosynthesis, the decomposition of calcium carbonate, and the melting of ice.
The energy change in a chemical reaction is called the enthalpy change (ΔH). A negative ΔH indicates an exothermic reaction (energy released), while a positive ΔH indicates an endothermic reaction (energy absorbed). Enthalpy change is a measure of the difference in heat content between the products and the reactants of a reaction.
Activation Energy: All chemical reactions, whether exothermic or endothermic, require an initial input of energy known as activation energy (Ea). This energy is needed to break the bonds in the reactants and initiate the reaction. Once the reaction starts, an exothermic reaction releases more energy than it requires, while an endothermic reaction absorbs more energy than it releases.
Key points:
- Chemical reactions involve the breaking and forming of chemical bonds.
- Chemical reactions can be either exothermic (release energy) or endothermic (absorb energy).
- The enthalpy change (ΔH) quantifies the energy change of a reaction.
- Activation energy (Ea) is the minimum energy required to initiate a chemical reaction.
- Energy diagrams can visually represent the energy changes in a chemical reaction, showing the relative energies of reactants, products, and the activation energy.