A topic from the subject of Inorganic Chemistry in Chemistry.

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Acid-Base Concepts in Chemistry

Key Points:



  • Acids donate H+ ions (protons), while bases accept H+ ions.
  • pH scale measures acidity or basicity, ranging from 0-14:

    • 0-6: Acidic
    • 7: Neutral
    • 8-14: Basic

  • Strong acids and bases completely dissociate in water, while weak acids and bases only partially dissociate.
  • Acids and bases undergo neutralization reactions, forming salts and water.
  • Conjugate acid-base pairs differ by the exchange of a proton.

Main Concepts:



  • Arrhenius Theory: Defines acids as substances that produce H+ ions and bases as substances that produce OH- ions in water.
  • Brønsted-Lowry Theory: Defines acids as proton donors and bases as proton acceptors.
  • Lewis Theory: Defines acids as electron-pair acceptors and bases as electron-pair donors.
  • pH: Negative logarithm of the H+ ion concentration, representing acidity or basicity.
  • pKa: Negative logarithm of the acid dissociation constant, indicating the strength of an acid.
  • Buffer Solutions: Solutions that resist pH changes by maintaining a constant H+ ion concentration.

Neutralization Reaction: An Acid-Base Experiment
Materials:

  • Hydrochloric acid (HCl) solution, 0.1 M
  • Sodium hydroxide (NaOH) solution, 0.1 M
  • Phenolphthalein indicator
  • 10 mL graduated cylinder
  • Erlenmeyer flask
  • Buret
  • Pipette
  • Safety goggles and gloves

Procedure:

  1. Wear appropriate safety gear.
  2. Fill a buret with the NaOH solution.
  3. Measure 10 mL of the HCl solution into an Erlenmeyer flask.
  4. Add 2-3 drops of phenolphthalein indicator to the HCl solution.
  5. Slowly add the NaOH solution from the buret to the HCl solution, swirling the flask constantly.
  6. Observe the color change of the indicator.
  7. Continue adding the NaOH solution until the indicator turns a faint pink color.
  8. Record the volume of NaOH solution used.

Key Procedures:

  • Use precise measurements to ensure accurate results.
  • Swirl the flask constantly during the titration to ensure thorough mixing.
  • Observe the color change of the indicator carefully to determine the endpoint.

Significance:

This experiment demonstrates the neutralization reaction between an acid (HCl) and a base (NaOH), resulting in the formation of a salt (NaCl) and water. It also introduces the concept of titration, a technique commonly used in chemistry to determine the concentration of unknown solutions.


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