Chemistry of Nonmetals
Experiment: Reaction of Sodium with Chlorine
Objective: To demonstrate the vigorous reaction between a metal and a nonmetal to form an ionic compound.
Materials:
- Sodium metal (small piece, about the size of a pea)
- Chlorine gas (in a sealed tube or container)
- Fire extinguisher (for safety)
- Safety goggles
- Lab coat
- Heat-resistant gloves
Procedure:
- Put on safety goggles, lab coat, and heat-resistant gloves.
- Place the small piece of sodium metal in a heat-resistant container.
- Carefully open the sealed tube or container of chlorine gas in a well-ventilated fume hood. Allow the gas to flow into the container with the sodium metal. (Note: This step should only be performed by trained personnel in a properly equipped laboratory.)
- Observe the reaction that occurs. Note the color of the flame and the appearance of the product.
- Once the reaction is complete, allow it to cool completely before handling. (No flame extinguishment is needed unless a fire occurs).
Results:
The reaction between sodium and chlorine is very vigorous, producing a bright yellow-orange flame and a white solid product. The solid product is sodium chloride (NaCl), an ionic compound. The reaction is highly exothermic.
Discussion:
The reaction between sodium and chlorine is a good example of the reactivity of nonmetals. Nonmetals readily combine with metals to form ionic compounds. In this reaction, the sodium atom donates an electron to the chlorine atom, forming a sodium ion (Na+) and a chloride ion (Cl-). These ions are then electrostatically attracted to each other, forming the ionic lattice structure of sodium chloride.
The balanced chemical equation for this reaction is: 2Na(s) + Cl2(g) → 2NaCl(s)
Safety Precautions:
This experiment involves highly reactive substances and should only be performed by trained personnel in a properly equipped laboratory with adequate safety measures in place. Chlorine gas is toxic and corrosive. Sodium metal reacts violently with water. Appropriate safety equipment and procedures are essential to avoid serious injury.
Significance:
The reaction between sodium and chlorine is a classic example of a chemical reaction between a metal and a nonmetal, illustrating the formation of an ionic compound. It highlights the electron transfer process in ionic bonding and the concept of balancing chemical equations. The reaction is also significant industrially in that, while not directly used for mass production of sodium chloride (NaCl), it demonstrates the fundamental chemistry behind the production of this ubiquitous salt.
Alternative Experiment (Safer Demonstration):
A safer demonstration of the reactivity of chlorine can be achieved by using a solution of chlorine water and reacting it with a solution of sodium bromide or iodide. The displacement of the halide ions and resultant color change provides a visual demonstration of chlorine's reactivity without the hazards of handling pure chlorine gas and sodium metal.